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Bound oxygen vs. Dissolved oxygen: There are two types of oxygen in the body-oxygen which is bound to hemoglobin and oxygen which is dissolved freely in the blood. Normal respiraton only involves transport of oxygen which is bound to hemoglobin. However, because hemoglobin is larger than the size of most capillaries in such vital organs as the lungs, kidneys, liver, and skin, hemoglobin-bound oxygen transport is not sufficient to attain full-body blood circulation.